When using the Claussius Clapeyron to solve for vapor pressure and calculating t
ID: 1011312 • Letter: W
Question
When using the Claussius Clapeyron to solve for vapor pressure and calculating temp. I don't understand the steps. Can you break down each step? I'm confused when I should convert and where to use dividing or multiplying. Example: Ethanol has a heat vaporization of 38.6 kilojoules/ mol and a normal boiling point of 78C. 1. Find the K intercept 2. What is the vapor pressure at 15CWhen using the Claussius Clapeyron to solve for vapor pressure and calculating temp. I don't understand the steps. Can you break down each step? I'm confused when I should convert and where to use dividing or multiplying. Example: Ethanol has a heat vaporization of 38.6 kilojoules/ mol and a normal boiling point of 78C. 1. Find the K intercept 2. What is the vapor pressure at 15C
Example: Ethanol has a heat vaporization of 38.6 kilojoules/ mol and a normal boiling point of 78C. 1. Find the K intercept 2. What is the vapor pressure at 15C
Explanation / Answer
Using the Clausius-Clapeyron equation.
ln(P2/P1)=(H/R)(1/T1-1/T2)
Here H is the heat of vaporization= 38.6 Kj= 38600 J
Here T1= 78 C = 78+273=351 K
T2= 15 C = 15+273= 288 K
ln(P2/760 torr)= 38600/8.314 (1/351-1/288)
ln(P2)-ln(760 torr)=4642.77(0.00063)
lnP2= -2.92 +lln 760
P2 = e^3.71
P2= 40.85 torr
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