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odnois ew.php?id 4842684 Mail yxg484@med....BankMobile: Open A... chase ing Jump to... Sapling Learning In a constant-pressure calorimeter, 55.0 ml of 0.340 M Ba(OH)2 was added to 55.0 ml of 0.680 M HC The reaction caused the temperature of the solution to rise from 23.84 to 28.47 . If the solution has the same density and specific heat as water (1.00 g/mL and 4.184 Jg·, respectively), what is AH for this reaction (per mole of H2O p Assume that the total volume is the sum of the individual volumes. 2Explanation / Answer
The reaction is as follows:
Ba(OH)2 + 2 HCl ---> BaCl2 + 2 H2O
Now, the above reaction is exothermic since the temperature of the solution increased.
To determine energy (in the form of heat) for a calorimeter (constant pressure) we can use the equation:
q= m x Csp x T
mass Ba(OH)2: 55.0 mL x 1 g = 55 g
mass HCl: 55.0 mL x 1 g = 55
mass solution = 55 g Ba(OH)2 + 55 g HCl = 110 g
q = 110 g x 4.184 J/gC x (28.47° C - 23.84 °C) =2130.91 J
Now, moles H2O = moles HCl reacted
therefore, 55 mL x 1 L x 0.680 mol x 1 mol H2O = 0.037 moles
So, H/mol H2O = 2130.91 J /0.037 moles H2O = 57592.1 J/mol = 57.6 kJ/mol
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