For each of the reactions below: Translate from words to the appropriate chemica
ID: 1031497 • Letter: F
Question
For each of the reactions below: Translate from words to the appropriate chemical formulas indicating the states for each substance. Balance the chemical equation with the appropriate coefficients. Write the molecular equation, ionic equation and the net ionic equation for each. Be sure to show all charges as well as states. In the ionic equation circle all spectator ions. If both products are aqueous salts the reaction will not proceed. For reactions like this, simply write N.R. (no reaction).
Aluminum metal reacts with a solution cadmium nitrite.
10. A 15.45 ml volume of 0.1327 M KMnO4(aq) is needed to oxidize 25.00 ml of a FeSO4(aq) in an acidic medium. What is molarity of the FeSO4(aq) given the following balanced net ionic equation:
5 Fe2+(aq) + MnO4-(aq) + 8H+(aq) ( Mn2+(aq) + 5Fe3+(aq) + 4H2O(aq)
Balance the following oxidation-reduction reaction by method of ½ reactions.
c) CN-(aq) + MnO4-(aq) ( CNO-(aq) + MnO2 [basic]
Explanation / Answer
9)
2Al(s) +3 Cd(NO3)2(aq) -------------------2 Al(NO3)3(aq) +3 Cd(s)
2 Al(s) + 3 Cd+2(aq) + 6 NO3-(aq) ------------- 2 Al+3(aq) + 6 NO3-(aq) + 3 Cd(s)
spectator ion is NO3-
2 Al(s) + 3 Cd+2(aq) -------------- 2 Al+3(aq) + 3 Cd(s)
10)
5 Fe2+(aq) + MnO4-(aq) + 8H+(aq) --------------- Mn2+(aq) + 5Fe3+(aq) + 4H2O(aq)
5 moles 1 mole
KMnO4 FeSO4
M1= 0.1327 M M2= ?
V1=15.45 mL V2= 25.00 ml
n1= 1 mole n2= 5 mole
M1V1/n1= M2V2/n2
0.1327x15.45/1 = M2x25.00/5
M2=0.410M
Molarity of FeSo4= 0.410M
c)
CN-(aq) + MnO4-(aq) ------------------- CNO-(aq) + MNO2
+2 -3 +7 -2 +4 -3 -2 +4 -2
Oxidation half reaction
CN- --------- CNO-
CN- + H2O ---------- CNO-
CN- + H2O + 2 OH- ------------ CNO- + 2 H2O
CN- + H2O + 2 OH- ----------- CNO- + 2 H2O + 2e-
Reduction half reaction
MnO4- ------------- MnO2
MnO4- -------------- MnO2 + 2 H2O
MnO4- + 4 H2O --------------- MnO2 + 2H2O + 4 OH-
MnO4- + 4 H2O + 3e- --------- MnO2 + 2 H2O + 4 OH-
[CN- + H2O + 2 OH- ----------- CNO- + 2 H2O + 2e-] x3
[MnO4- + 4 H2O + 3e- --------- MnO2 + 2 H2O + 4 OH-]x2
3CN- +3 H2O + 6 OH- -----------3 CNO- + 6 H2O + 6e
2 MnO4- + 8 H2O + 6e- --------- 2 MnO2 + 4 H2O + 8 OH-
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3 CN- + 2 MNO4- + 2H2O ---------------- 3 CNO- + 2 MNO2 + 2 OH-
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