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Experimental pKa values Literature pKa values (malonic) Percent error 2.52 2.82

ID: 1035527 • Letter: E

Question

Experimental pKa values

Literature pKa values (malonic)

Percent error

2.52

2.82

10.6%

5.39

5.69

5.27%

Literature pKa values (oxalic)

Percent error

na

1.23

130%

na

4.19

28.6%

Literature pKa values (phthalic)

Percent error

na

2.89

10.64%

na

5.51

2.18 %

Experimental molar mass

Literature molar mass (malonic)

Percent error

8.779

8.51

10.64

na

Literature molar mass (oxalic)

Percent error

na

5.42

158.6

na

Literature molar mass (phthalic)

Percent error

na

8.40

12.82

HELP!!!! this part at the bottom

(3 points) Sum the % error for each diprotic acid in the table below.

Diprotic acid

% error pKa-1

% error pKa-2

% error molar mass

Total % error

Malonic

Oxalic

Phthalic

Experimental pKa values

Literature pKa values (malonic)

Percent error

2.52

2.82

10.6%

5.39

5.69

5.27%

Literature pKa values (oxalic)

Percent error

na

1.23

130%

na

4.19

28.6%

Literature pKa values (phthalic)

Percent error

na

2.89

10.64%

na

5.51

2.18 %

Explanation / Answer

Total percent Error for a sent of 'n' variables which have individual percent errors as E1 , E2, E......, En is given as the average of individual percent errors i.e (E1 + E2 + E...... + En ) / n.

For Malonic acid (10.6 + 5.27 + 10.64) / 3 = 8.83%

For Oxalic acid ( 130 + 28.6 + 158.6 ) / 3 = 105.73%

For pthalic acid (10.64 + 2.18 + 12.82 ) / 3 = 8.54%

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