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Question

"Waiting for response from session.masterlhgetemisly 2 https://session.masteringchemistry.com/myct/itemView?assignmentProblemiD-943909868toffset-ne K Homework 39 EOC 17 Problem 17.106 Part A How many hours are required to produce 1000 kg of sodium by the electrolysis of molten NaCl with a constant current of 2.50 10" A Submit Previous Answers Request Answer Incorrect, Try Again; 5 attempts remaining Part B How many liters of Clh at STP will be obtained as a by-product? Vcls Submit Provide Feedback

Explanation / Answer

mass of sodium = W= 1000Kg

molar mass of sodium = 23.0grams/mole = 0.023 Kg/mole=M

valency of Soidum = Z=1

current = C= 2.50x10^4 A

Faraday = F = 96500 coloubs

according to faradays laws

W= Mct/ZF

1000 = 0.023x2.50x10^4xt/1x96500

t= 46.618 hours.

Time required for the production of Na= 46.618 hours

Part-B

molar mass of Cl2 = 71 grams

valency = Z=1

c=2.50x10^4A

time= 46.619=8 hours= 46618.36 sec

W=Mct/ZF

W= 71 x2.50x10^4x46618.35/1x96500=857487.78 grams

mass of Cl2 formed= 857487.78 grams

At STP one mole of gas occupies 22.4 L of volume

i.e 71 grams of Cl2 occupies = 22.4 L

857487.78 grams of Cl2 = ?

                                     = 22.4x857487.78/71=270531.35L

volume of Cl2 = 270531.35L