numbers? For a set that is invalid, explain bniefly why it is not correct. ion (

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numbers? For a set that is invalid, explain bniefly why it is not correct. ion (b) n 2, 1, me- red 35. What is the maximum number of orbitals that can be (d)-4,3,me identified by each of the following sets of quantum numbers? When "none" is the correct answer, explain your reasoning. on 2 thr (b) -5, e 1 d)4, 2, me-2 36. What is the maximum number of orbitals that can be mol identified by each of the following sets of quantum numbers? When “none" is the correct answer, explain your reasoning (a) n= 4, e-3 (b)nS as (c)n 2,e-2 (d) n-3,e 1,me 37. Explain briefly why each of the following is not a pos- sible set of quantum numbers for an electron in an atom In each case, change the incorrect value (or values) to make the set valid. b) 3, 38. Explain briefly why each of the following is not a pos- sible set of quantum numbers for an electron in an atom. In each case, change the incorrect value (or values) to make the set valid. (a) n 2, -2, me 0, m, +h 1-2,e1, = State which of the following orbitals cannot exist accord ing to the quantum theory: 2s, 2d, 3p, 3f, 4f, and Ss. 39. Briefly explain your answers. l40. State which of the following orbitals cannot exist ac n Q the quantum theory: 3p, 4s, 2f, and 1p. Briefl

Explanation / Answer

(a) L= can have n-1 values only so n cannot be equal to L

(b) ms can assume values to be +1/2 or -1/2 cannot be zero

(c) ml can assume values from -L to +L, thus -2 is not possible

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