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Use the References to access important values If needed for this question. An el

ID: 1045968 • Letter: U

Question

Use the References to access important values If needed for this question. An electrochemical cell consists of a PtH (aq, 1.00 M)I12(8) cathode connected to a PijH (aq)IH2(8) anode in which the H concentration is that of a buffer consisting of a weak acid, HA(0.152 MM, mixed with its conjugate base, A-(0.187 M). The measured cell voltage is E cell = 0.247 V at 25 °C, with PH, -1.00 atm at both electrodes. Calculate the pit in the buffer solution and the K, of the weak acid. Ka Submit Answer 5 question attempts remaining

Explanation / Answer

Ecell = Eo + 0.05916 pH

Eo = 0

Ecell = 0.05916 pH

pH = Ecell / 0.05916

    = 0.247 / 0.05916

pH = 4.18

pH = pKa + log [A- / HA]

4.18 = pKa + log [0.187 / 0.152]

pKa = 4.09

Ka = 8.13 x 10^-5