Given the following data for this reaction:2A + B rightarrow C + D Calculate the

Question

Given the following data for this reaction:2A + B rightarrow C + D Calculate the order of the reaction with respect to A Calculate the order of the reaction with respect to B What is the overall order of the reaction For following reaction at equilibrium, which gives a change that will shift the position of the equilibrium to favor formation of more products? 2NOBr_(g) doubleheadarrow 2NO(g) + Br_2(g)6 delta H _ = 30 kJ/mol Increase the total pressure by decreasing the volume. Add more No. Remove Br_2. Lower the temperature. Remove NOBr selectively.

Explanation / Answer

1)
a)
look at experiment 1 and 2
[A] doubles
[B] doesn't change
rate becomes 4 times

so, order of [A] is 2

b)
look at experiment 2 and 3
[A] doesn't chnage
[B] doubles
rate doesn't change

so, order of [B] is 0

c)
overall order = order of A + order of B
= 2 + 0
= 2

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