(A)Calculate, in units of ?, the magnitude of the maximum orbital angular moment
ID: 1387783 • Letter: #
Question
(A)Calculate, in units of ?, the magnitude of the maximum orbital angular momentum for an electron in a hydrogen atom for states with a principal quantum number of 9.00.
(B)Calculate, in units of ?, the magnitude of the maximum orbital angular momentum for an electron in a hydrogen atom for states with a principal quantum number of 41.0.
(C)Calculate, in units of ?, the magnitude of the maximum orbital angular momentum for an electron in a hydrogen atom for states with a principal quantum number of 206.
(D)Compare each with the value of n? postulated in the Bohr model. What trend do you see?
Explanation / Answer
The magnitude of the orbital angular momentum of the electron depends on the orbital quantum number l as
L = sqrt( l(l+1) ) hbar Where hbar = 1.0546*10-34 J.s
For given principal quantum number n, the maximum value of l is n-1.( l= 0, 1, 2, ..., n-1).
So for given n, the maximum magnitude of orbital angular momentum is
L_max = sqrt(( n-1)n ) hbar
With n=41,
L_max= sqrt(40 *41) hbar = 40.497* hbar
With n= 9,
L_max = sqrt(8* 9) hbar = 8.485* hbar
With n= 206,
L_max = sqrt(205 *206) hbar= 205.499* hbar
Note that for large n, sqrt( n ( n-1)) approximately equals n.
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