BIOCHEMISTRY QUESTION 3.)Which of the following pairs of functional groups are p
ID: 144048 • Letter: B
Question
BIOCHEMISTRY QUESTION
3.)Which of the following pairs of functional groups are present in the molecule below? NOTE: C is grey, N is blue, O is red, H is white
A-Carboxylic acid; amine
B-Aldehyde; carboxylic acid
C-aldehyde;amine
D-anhydride;hydroxyl
E-carboxylic acid; anhydride
2.)Which of the following has the elements in the correct order of increasing electronegativity?
A- O<N<P<C
B- C<P<N<O
C- P<C<N<O
D- C<N<P<O
E- C<N<O<P
1.) Fructose 1,6-bisphosphate (F1,6BP) is converted to D-Glyceraldehyde-3-phosphate (GADP) and Dihydroxyacetone phosphate (DHAP) during glycolysis, with a standard free-energy change (delta G'°) of 23.8 kJ/mol. Which of the following conditions encountered in a normal cell will result in a spontaneous reaction in the forward direction?
A- Standard conditions. Enough energy is released for the forward reaction to be spontaneous.
B- No conditions. The reaction cannot proceed spontaneously under any conditions due to the high positive delta G'°.
C- A high concentration of DHAP and GADP relative to the concentration of F1,6BP.
D- A high concentration of F1,6BP relative to the concentration of DHAP and GADP.
E- High concentrations of the enzyme that catalyzes the reaction.
0.) You add 100mL of 0.5 M acetic acid to 400 mL of 0.5 M NaOH. The final pH is:
note:- The pKa of acetic acid is 4.76.
A- 4.76
B- 5.76
C- 9.82
D- 12.48
E- NOT ENOUGH INFORMATION
Explanation / Answer
O.D.12.48
Addition of 200 mmol of NaOH (400 mL ´X 0.5 M) to 50 mmol of acetic acid (100 mL X 0.5 mM) completely titrates the acid so that it can no longer act as a buffer and leaves 150 mmol of NaOH dissolved in 500 mL, an [OH–] of 0.3 M.
Given [OH–], [H+] can be calculated from the water constant:
[H+][OH–] = 10–14
[H+] = 10–14 M2 / 0.3 M
pH is, by definition, log (1/[H+])
pH = log (0.3 M /10–14 M2) = 12.48.
2.c.
P<C<N<O.
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