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%% BEGIN BY CALCULATING THE NUMERICAAL VALUE FOR \"nR\" A closed, hydrostatic, i

ID: 3279252 • Letter: #

Question

%% BEGIN BY CALCULATING THE NUMERICAAL VALUE FOR "nR"

A closed, hydrostatic, ideal-gas system is caused to follow the following reversible cycle To prevent round-off errors in the calculations, report all answers to four (4) significant figures. (a) Calculate reversible work (w), reversible heat flow (q), and Delta U (extensive: value, sign, units in liter-atm) for each path (a, b, c, d). Summarize in a neat table the results for w, q, and Delta U for each path segment and for the entire cyclic process. (b) Calculate "Efficiency" for the cyclic process: Efficiency = (net)work done by the system/heat input to the system Write the expression as a function of T_1, T_2, T_3, and T_4, and then calculate the numerical result for this process.

Explanation / Answer

nR = PV/T =1*6/300 = 1/50

assume it is monoatomic gas PV^1.67 = constant

P2/P1 = (V1/V2) ^1.67

P2 = 1 *(6/1)^1.67 = 19.93 atm

T2 = P2V2/nR = 19.93*1*50

= 996.5 K

again P3 = nRT3/V3 = 1100/(1*50) = 22 atm

P4 =22* (1/6)^1.67 = 1.104 atm

T4 = P4V4/nR

= 1.104*6*50 = 331.5 T

now Wa = delta [PV]/[1- gamma] = [19.93*1-6*1]/-0.667 =- 20.89 litre atm

Ua = 1.5*delta [PV] = [19.93*1-6*1]/0.667 = 20.89 litre atm

qa = 0

similarly Wb = 0

Ub = 1.5*[19.93-22*1] = 3.105 litre atm

qb = ub = 3.105 litre atm

now again, wc = [1.104*6 - 22*1]/[1.67-1] = 22.95 litre atm

qc = 0

uc = -22.95 litre atm

wd = 0

ud = 1.5*[1*6-1.104*6] = -0.936 litre atm

qd = -0.936 litre atm

b] efficiency = total work done*100/total heat given = [wc +wa]/qd = work done in process C and A/ heat given in process b

= [ 22.95-20.89]*100/[3.105]

= 66 %