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Complete the following sentences on predicting the relative entropy of a system.

ID: 486395 • Letter: C

Question

Complete the following sentences on predicting the relative entropy of a system.

The words are: decreases, equal to, increases, less than, greater than

1. Temperature Changes: for a given substance, S° __________as the temperature increases.

2. Physical States and Changes of State: as the freedom of motion of the substance  ____________ , the entropy increases. The size of the entropy change is such that S°vap is much  ____________  S°fus .

3. Dissolving a Gas: when a gas dissloves in a liquid, the entropy always  ____________  but when disolved in another gas it  ____________ .

4. Dissolving a Solid or a Liquid: the entropy of a dissolved solid or liquid is always  ____________  the entropy of the pure substance.

5. Atomic Size: the entropy of atoms generally  ____________  down a group since the number of microstates  ____________ .

6. Molecular Complexity: the entropy of molecules  ____________  as they become more complex and the number of atoms  ____________ .

Explanation / Answer

1. Temperature Changes: for a given substance, S° increases as the temperature increases.

2. Physical States and Changes of State: as the freedom of motion of the substance increases, the entropy increases. The size of the entropy change is such that S°vap is much greater than S°fus .

3. Dissolving a Gas: when a gas dissloves in a liquid, the entropy always decreases but when disolved in another gas it increases .

4. Dissolving a Solid or a Liquid: the entropy of a dissolved solid or liquid is always greater than the entropy of the pure substance.

5. Atomic Size: the entropy of atoms generally   increases down a group since the number of microstates   increases.

6. Molecular Complexity: the entropy of molecules increases as they become more complex and the number of atoms increases .

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