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Consider the following reaction: 2NO(g)+2H2(g)N2(g)+2H2O(g). Part A The rate law

ID: 506381 • Letter: C

Question

Consider the following reaction:
2NO(g)+2H2(g)N2(g)+2H2O(g).

Part A

The rate law for this reaction is first order in H2 and second order in NO. Write the rate law.

Part B

If the rate constant for this reaction at 1000 K is 6.0×104M2s1, what is the reaction rate when [NO]= 4.00×102M and [H2]= 1.10×102M?

Express your answer using two significant figures and in M/s

Part C

What is the reaction rate at 1000 K when the concentration of NO is increased to 0.15 M, while the concentration of H2 is 1.10×102M?

Express your answer using two significant figures and in M/s

rate=k[H2][NO] rate=k[H2][NO]2 rate=k[H2]2[NO]2 rate=k[H2]

Explanation / Answer

Rate = k*[H2]^a [ NO]^b

if [H2] = first order, then a = 1

if [NO] is second order, then b = 2

hence

Rate = k*[H2]^a [ NO]^b

Rate = k*[H2]^1 [ NO]^2

Rate = k*[H2][ NO]^2

B)

if K = 6*10^4 1/M2s, then find rate at

[NO] = 4*10^-2 and [H2] = 1.1*10^-2

simply

substitute in

Rate = k*[H2][ NO]^2

Rate = (6*10^4)*(1.1*10^-2)*(4*10^-2)^2

Rate 1.056 M/s

C

find rate when

[NO] increases to 0.15 M and [H2] = 1.1*10^-2

from

Rate = k*[H2][ NO]^2

Rate = (6*10^4)(1.1*10^-2)(0.15^2)

Rate = 14.85 M/s

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