In analyzing an unknown salt containing one of the following anions: Br^-, Co3^2
ID: 511271 • Letter: I
Question
In analyzing an unknown salt containing one of the following anions: Br^-, Co3^2-, Cl^-, I^-, NO3^-, NO2^-, PO4^3-, SO4^2-, SO3^2-, why might a student obtain negative results for all three of the following classification reactions?
Classification Reaction 1: Formation of insoluble salts, such as BaCO3, BaSO4, BaSO3, Ba3(PO4)2
Classification Reaction 2: Formation of volatile products when H3O^+ ion is added to such anions as CO3^2-, NO2^-, SO3^2- ions
Classification Reaction 3: Formation of insolube silver salts, such as AgBr, AgCl, AgI
Explanation / Answer
Classification Reaction 1:
If there is not formation of insoluble salts then there is possibility of presence of nitrate ion (NO3-),as salts containing nitrate ions are generally soluble in water
Classification Reaction 2: Formation of volatile products when H3O^+ ion is added to such anions
Due to oxidizing nature of nitrate ions, they interfere with the with the formation of volatile products on addition of acid.
Classification Reaction 3: Nitrate ions form soluble salt with silver and due to oxidizing nature it interfere with the results and give us fake / erroneous results.
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