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The value of enthalpy for the following reaction is -52.0 kJ/mol NH3 (aq) + HCl

ID: 515126 • Letter: T

Question

The value of enthalpy for the following reaction is -52.0 kJ/mol NH3 (aq) + HCl (aq) ---> NH4Cl(aq) Estimate the increase in temperature that will occur when 100.0mLs of .50M ammonia in a styrofoam container is neutralized by 300 mLs of a solution containing excess HCl. The value of enthalpy for the following reaction is -52.0 kJ/mol NH3 (aq) + HCl (aq) ---> NH4Cl(aq) Estimate the increase in temperature that will occur when 100.0mLs of .50M ammonia in a styrofoam container is neutralized by 300 mLs of a solution containing excess HCl. NH3 (aq) + HCl (aq) ---> NH4Cl(aq) Estimate the increase in temperature that will occur when 100.0mLs of .50M ammonia in a styrofoam container is neutralized by 300 mLs of a solution containing excess HCl.

Explanation / Answer

No of mol of NH3 =( 0.5mol /1000)× 100ml = 0.05mol

Heat of neutralization = -52KJ/mol = -52000J/mol

For 0.05 mol Heat released = (-52000/1)×0.05= - 2600J

Heat capacity of water = 4.18 J/gmol

Mass of water = 400g

q = m× T × C

2600 J = 400g × T × 4.18(J/g K )

T = 1.55

Therefore, Increase in temperature is 1.55