Question 31 Which of the following insecticides is formed by Diels Alder reactio
ID: 532320 • Letter: Q
Question
Question 31
Which of the following insecticides is formed by Diels Alder reaction of hexachlorocyclopentadiene and how do you know that Briefly explain why there is such a vast number of insecticides ... 20 words can easily be enough. Pyrethrin insecticides are said to be "natural" type insecticides. Why? What structural feature is found in synthetic pyrethroids, like permethrin ..? What is the class of pesticides that is causing some much trouble for bees? How did Cousteau and friends probably get exposed to PCBs? How did Gavin get exposed, probably, to PBDEs? How do Orcas get exposed to PCBs ad PBDEs? Draw an example of a PCB congener and an example of a PBDE congener.Explanation / Answer
Ans 31.
The first structure is formed as the product of diels alder reaction of hexa chlorocyclopentadiene.
The reaction involves halogen containing alkenes as dienophiles and occurs only when atleast one hydrogen atom is attached to the double bond.
The reaction with thiones will yield the formation of [2+4] cycloadducts like this.
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