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2.Experimental Procedure, Parts A.4, 5 a. When a metal at a higher temperature i

ID: 546377 • Letter: 2

Question

2.Experimental Procedure, Parts A.4, 5 a. When a metal at a higher temperature is transferred to water at a lower temperature, heat is inevitably lost to the calorimeter (Figure 25.4). Will this unmeasured heat loss increase or decrease the calculated value of the specific heat of the metal? Explain. See equation 25.5. b. Explain why the extrapolated temperature is used to determine the maximum temperature of the mixture rather than the highest recorded temperature in the experiment. See Figure 25.5.

Explanation / Answer

Q2a

for the metal, we will have the next balance

Qmetal = Qliquid

if there is a loss:

Qloss + Qmetal = Qliquid

Qmetal = Qliquid - Qloss

therefore, (Qliquid - Qloss) is lower

meaning that

Qmetal will be calcualted LOWER

Qmetal = mmetal * Cp metal ¨(Tf-Tmetal)

if Tf, Tmeta lare fixed, and mass of metal won't change

then Cp metal must decrease

meaning that the Cp clacualted will be LOWER is there is any heat loss

b)

extrapolation is needed when we do NOT have values/constants/data on the range given

we avoid the "highest" temperature, since it is not reliable due to the thermometer calibration

it is much better to "extrapolate" specially if there is no data present