I need help answering this question. It says Mass OF NH4Cl should the student di
ID: 547153 • Letter: I
Question
I need help answering this question. It says Mass OF NH4Cl should the student dissolve in the NH3 solution that turns into a BUFFER with a ph of 9.76.. You can assume the solution wont change when the NH4CL dissolves. Please show your full work, and answer in 2 significant digits.
A chemistry graduate student is given 300 mL of a 0 40 M ammonia NH3) solution. Ammonia is a weak base with K,-1.8 × 10 NH4Cl should the student dissolve in the NH3 solution to turn it into a buffer with pH 9.76? . What mass of You may assume that the volume of the solution doesn't change when the NH4CI is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 significant digits. x10Explanation / Answer
Kb = 1.8*10^-5
pKb = - log (Kb)
= - log(1.8*10^-5)
= 4.7447
POH = 14 - pH
= 14 - 9.76
= 4.24
use formula for buffer
pOH = pKb + log ([NH4Cl]/[NH3])
4.24 = 4.7447 + log ([NH4Cl]/[NH3])
log ([NH4Cl]/[NH3]) = -0.5047
[NH4Cl]/[NH3] = 0.3128
[NH4Cl] = 0.1251
volume , V = 300.0 mL
= 0.3 L
number of mol,
n = Molarity * Volume
= 0.1251*0.3
= 3.754*10^-2 mol
Molar mass of NH4Cl,
MM = 1*MM(N) + 4*MM(H) + 1*MM(Cl)
= 1*14.01 + 4*1.008 + 1*35.45
= 53.492 g/mol
mass of NH4Cl,
m = number of mol * molar mass
= 3.754*10^-2 mol * 53.492 g/mol
= 2.008 g
Answer: 2.0 g
Feel free to comment below if you have any doubts
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