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The following data represents the oxygen binding activity of purified myoglobin,

ID: 55440 • Letter: T

Question

The following data represents the oxygen binding activity of purified myoglobin,

purified hemoglobin, and hemoglobin in human blood cells.

pO2 (Torr)

Fraction of purified myoglobin with O2

pO2(Torr)

Fraction of purified hemoglobin with O2

pO2(Torr)

Fraction of Hemoglobin in blood with O2

0.5

0.161

0.1

.00315

10.6

0.10

1.0

0.277

0.35

.0099

19.5

0.30

2.0

0.434

0.794

.0306

27.4

0.50

3.0

0.535

1.748

.0909

37.5

0.70

4.0

0.605

2.884

.24

50.4

0.85

6.0

0.697

4.467

.50

77.3

0.96

8.0

0.754

5.75

.76

92.3

0.98

12

0.821

7.94

.909

20

0.885

12.88

.969

29.51

.99

67.60

.997

A) Construct the oxygen binding curves of purified myoglobin and hemoglobin and

hemoglobin in blood cells and estimate p50 of myoglobin and hemoglobin under these conditions.

B) Estimate Hill coefficient (n) of purified hemoglobin and hemoglobin in blood cells.

pO2 (Torr)

Fraction of purified myoglobin with O2

pO2(Torr)

Fraction of purified hemoglobin with O2

pO2(Torr)

Fraction of Hemoglobin in blood with O2

0.5

0.161

0.1

.00315

10.6

0.10

1.0

0.277

0.35

.0099

19.5

0.30

2.0

0.434

0.794

.0306

27.4

0.50

3.0

0.535

1.748

.0909

37.5

0.70

4.0

0.605

2.884

.24

50.4

0.85

6.0

0.697

4.467

.50

77.3

0.96

8.0

0.754

5.75

.76

92.3

0.98

12

0.821

7.94

.909

20

0.885

12.88

.969

29.51

.99

67.60

.997

Explanation / Answer

A) P50 is that pO2 (Torr) where the fraction of the protein ( here myoglobin and hemoglobin) with 0.5 or 50% O2.

Thus, from the above data, P50 for myoglobin = 2.7

and P50 for hemoglobin = 4.467

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