Consider the options below and enter the number that best satisfies the boldface
ID: 561714 • Letter: C
Question
Consider the options below and enter the number that best satisfies the boldfaced statement on your answer sheet. Enter 1 if the first option applies, 2 if the second option applies, “N” if NEITHER option applies, or “B” if BOTH options applyPlease be careful when answering these questions because they are meant to be abnormally hard and trick you. If PhBr was in the stockroom then (Ph)-Culi True False i) Vs could be an "Off the Shelf" reagent Will reduce Pyruvic Acid to a 2° alcohol Grignards perform conjugate addition with LiAIH4 NaBH vs False k) True vs MVK
Explanation / Answer
(i)
(1) Ture
Bromobenzene can be kept on stockroom but (Ph)2CuLi, it is a Gilmann reagent and it is very reactive and should be kept in an isolated place.
(j)
(1) LiAlH4
LiAlH4 reduces the carboxylic acid but NaBH4 can only reduce aldehydes and ketones.
(k)
(2) False
Grignard reagent adds in 1,2 addition where as gilmann reagent adds as 1,4-addition.
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