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Using the table below, and the three bulleted points below. Calculate the net yi

ID: 56368 • Letter: U

Question

Using the table below, and the three bulleted points below. Calculate the net yield of ATP (assuming 4H+ are required for the synthesis of 1 ATP via ATP Synthase) from the complete oxidation of C14:0. Indicate the number of ATP (generated through substrate-­level phosphorylation), Acetyl CoA, NADH, and FADH2 that are generated through this process.The net production should account for the “activation” of fatty acid by Acyl CoA Synthetase (equivalent to 2ATP).

•Total H+ produced through complete oxidation of C14:0 (from table below):

•Total Possible ATP based on number of H+ produced:

•Net ATP Produced from complete oxidation of C14:0

Total Number of Product

Molecules Produced

Total Number of H+ Produced in Electron Transport Chain

Atp

(from substrate-level phosphorylation in TCA cyle)

Product

Total Number of Product

Molecules Produced

Total Number of H+ Produced in Electron Transport Chain

List Enzyme(s) Responsible for Product Generation Subcellular Localization

Atp

(from substrate-level phosphorylation in TCA cyle)

Not applicable Acetyl CoA (from Beta-oxidation) Not applicable NADH ( from Beta-oxidation) NADH ( from TCA Cycle) FADH2 (from Beta-oxidation) FADH2 (from TCA Cycle)

Explanation / Answer

Fatty acids undergo - oxidation i.e. oxidative removal of successive two-carbon units in the form of acetyl CoA. Thus the conversion of C 14:0 will yield 7 acetyl CoA (six passes of - oxidation occurs here).

Each pass through - oxidation gives one molecule of acetyl CoA, two pairs of electrons, and four protons.

Overall equation :

C14 :0 ------------à    7 acetyl CoA + 6FADH2 + 6NADH

Each molecule of FADH2 gives 1.5 molecule of ATP.

Each molecule of NADH gives 2.5 molecule of ATP.

Each acetyl CoA yields 1GTP (=ATP), 3 NADH,1FADH2

In total we have,

13 FADH2 + 27 NADH + 7 GTP (=ATP) = 94 ATP

Energetic cost of activating a fatty acid = 2 ATP

Hence net gain of ATP = 92 ATP