For the following overall reation: 2A + B + C ---> products we can get the follo
ID: 632279 • Letter: F
Question
For the following overall reation: 2A + B + C ---> products
we can get the following data (in respective order):
[A] mol/L = 0.10, 0.20, 0.20, 0.10, 0.40
[B] mol/L = 0.10, 0.10, 0.20, 0.10, 0.20
[C] mol/L = 0.10, 0.10, 0.10, 0.20, 0.20
Rate = 1.64x10^-3, 3.19x10^-3, 1.28x10^-2, 1.62x10^-3, 2.66x10^-2
What is the order of the reaction with respect to [A] ? [B] ? [C] ?
What is the rate law expression for the above reation?
rate = ?
What is the rate constat from the above data for this reaction?
k=
Explanation / Answer
Let rate = k [A]^x [B]^y [C]^z
1.64x10^-3 =k [.1]^x [.1]^y [.1]^z..................................1
3.19x10^-3 =k[.2]^x [.1]^y [.1]^z..................................2
1.28x10^-2 =k[.2]^x [.2]^y [.1]^z...................................3
1.62x10^-3 =k[.1]^x [.1]^y [.2]^z..................................4
2.66x10^-2 =k.[.4]^x [.2]^y [.2]^z..................................5
debide 1 and 2
1.95 = 2^x
x=order with respect to A = 0.95 =1
devide 2 and 3
2.49 =1/2^y
2^y = 1/2.49
y = order with respect to B = -1.31
devide 1 and 4
1.01 = 1/2^z
2^z=1/1.01
z = order with respect to C = 0
Rate = k*[A]^1[B]^(-1.31)
from 1
k= 33.48*10^(-3)
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