collecting the distillate in ice sodium bicarbonate extraction water extraction

Question

collecting the distillate in ice sodium bicarbonate extraction water extraction anhydrous sodium or magnesium sulfate. Why do tertiary alcohols react faster with concentrated hydrochloric acid than do secondary or primary alcohols? Why are rearrangements rare with tertiary alcohols but not with secondary or primary alcohols? Compare the IR spectra of the reactant and final product of this experiment. Would you expect the peak due to the (CH3)3C - group in the 1H NMR spectrum of the product to have a greatly different chemical shift from the corresponding chemical shift seen in the 1H NMR spectrum of the reactant? Explain.

Explanation / Answer

they both will have different chemical shifts as both are of diffrent electro negativity

chemical shift of tertiary chlorides should be more than tertiary alchohols as chlorides are more electronegativity

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