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At 40 C H2O2(aq) will decompose according to the followingreaction: 2H2O2 (aq) -

ID: 678199 • Letter: A

Question

At 40 C H2O2(aq) will decompose according to the followingreaction: 2H2O2 (aq) -----> 2H2O (l) + O2 (g)
The following data were collected for the concentration ofH2O2 at various times:
   Time (s)    H2O2 (mol/L)    0       1.000    2.16 x 104      0.500    4.32 x 104    0.250
a) calculate the average rate of decomposition of H2O2 between0 and 2.16 x 104 s. Use this rate to calculate the averagerate of production of O2 (g) over the same time period.
b) what are these rates for the time period 2.16 x 104 s to4.32 x 104 s ?
Show all work please 2H2O2 (aq) -----> 2H2O (l) + O2 (g)
The following data were collected for the concentration ofH2O2 at various times:
   Time (s)    H2O2 (mol/L)    0       1.000    2.16 x 104      0.500    4.32 x 104    0.250
a) calculate the average rate of decomposition of H2O2 between0 and 2.16 x 104 s. Use this rate to calculate the averagerate of production of O2 (g) over the same time period.
b) what are these rates for the time period 2.16 x 104 s to4.32 x 104 s ?
Show all work please

Explanation / Answer

From the equation ,       Rate law is -1/2 [H2O2] / t =   1/2 [H2O] /t =   [O2] / t .   a ) Average rate of decomposition = - ( 0.5 - 1 ) mol / L / 2* 2.16 x 104 s.- 0 s                                                         =    0.5 mol / L /2* 2.16 x 104 s                                                         =     0.11 * 10 ^ -4 mol / L.s                                                         =     1.1 * 10 ^ -5 mol / L.s Average rate of production of O2 (g ) =  2 * Average rate of decomposition ofH2O2                                                            = 2 *  1.1 * 10 ^ -5 mol / L.s                                                            = 2.2 * 10 ^ -5 mol /L.s b)   Average rate of decomposition = - ( 0.250 - 0.5 ) mol / L / 2( 4.32*10^4- 2.16 x 104 s )                                                       =    0.0578 * 10 ^ -4 mol / L.s                                                       =    5.78 * 10 ^ -6 mol / L.s Average rate of production of O2 (g ) = 2 * 5.78 *10 ^ -6 mol / L.s                                                            =11.56 * 10 ^ -6 mol / L.s
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