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The compound CF 3 CHClF is being considered as areplacement for CBrF 3 as a fire

ID: 683557 • Letter: T

Question

The compound CF3CHClF is being considered as areplacement for CBrF3 as a fire-extinguishing agentbecause CBrF3 has been shown to deplete stratosphericozone. What are the most probable products if a molecule ofCF3CHClF is bombarded with high-energy photons? Please EXPLAIN your answer. A. CF3 + CHClF B. CF2CHClF + F C. CF3CHF + Cl D. CF3CClF + H                                                                            Bond                          Bond Energy, kJ mol-1                                                                            C-C                                346                                                                            C-Cl                                327                                                                               C-F                                485                                                                            C-H                                411 The compound CF3CHClF is being considered as areplacement for CBrF3 as a fire-extinguishing agentbecause CBrF3 has been shown to deplete stratosphericozone. What are the most probable products if a molecule ofCF3CHClF is bombarded with high-energy photons? Please EXPLAIN your answer. A. CF3 + CHClF B. CF2CHClF + F C. CF3CHF + Cl D. CF3CClF + H                                                                            Bond                          Bond Energy, kJ mol-1                                                                            C-C                                346                                                                            C-Cl                                327                                                                               C-F                                485                                                                            C-H                                411                                                                            C-C                                346                                                                            C-Cl                                327                                                                               C-F                                485                                                                            C-H                                411

Explanation / Answer

We Know that :    Lower the bond - dissociation energy easier tocleave the the bond between the atoms.     When CF3CHClF is bombared withhigh - energy photon the Product C is formed as the cleavageof C-Cl bond      is very easy which can be interpretedfrom their bond energy.          CF3CHClF   + photon ---------> CF3CHF + Cl
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