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The volume of a sample of pure HCl gas wass 189mL at 25C and108mmHg. It was comp

ID: 685909 • Letter: T

Question

The volume of a sample of pure HCl gas wass 189mL at 25C and108mmHg. It was completely dissolved in about 60mLof water andtitrated with an NaOh soution; 15.7mL of the NaOH solution wererequired to neutralize the HCl. Calculate the molarity of the NaOHsolution. Is the reaction: HCl + H2O + NaOH -> NaCl + 2H2O The volume of a sample of pure HCl gas wass 189mL at 25C and108mmHg. It was completely dissolved in about 60mLof water andtitrated with an NaOh soution; 15.7mL of the NaOH solution wererequired to neutralize the HCl. Calculate the molarity of the NaOHsolution. Is the reaction: HCl + H2O + NaOH -> NaCl + 2H2O

Explanation / Answer

HCl + NaOH => NaCl   +   H2O moles HCl:   n = PV/RT = (108 mmHg * 1 atm/ 760 mmHg) *(0.189 L)/ (0.0821 L*atm/mol-K * 298K) n = 0.001097773 moles HCl => 0.001097773 moles NaOH required   b/c of 1:1stoichiometry [NaOH] = 0.001097773 mol / 0.0157 L = 0.0699218471 = 0.0699 MNaOH

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