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and can you tell me why it is either diamagnetic or paramagneticplease (a) RuO 1

ID: 689878 • Letter: A

Question

and can you tell me why it is either diamagnetic or paramagneticplease

(a) RuO 1 diamagnetic paramagnetic    
(b) CuCl 2 diamagnetic paramagnetic    
(c) NiCl2 3 diamagnetic paramagnetic    
(d) Mo2O3 4 diamagnetic paramagnetic    
(e) NbCl5 5 diamagnetic paramagnetic     1 diamagnetic paramagnetic     1 diamagnetic paramagnetic     1 2 diamagnetic paramagnetic     2 diamagnetic paramagnetic     2 3 diamagnetic paramagnetic     3 diamagnetic paramagnetic     3 4 diamagnetic paramagnetic     4 diamagnetic paramagnetic     4 5

Explanation / Answer

   a) The given compoundis   RuO        Here Ru oxidation stateis +2 state (Ru2+ )        The Electroniccofiguration of Ru2+ is4d65s0        Here the number ofUnpaired electrons is 4.      'n' is the number of unpairedelectrons.        Magnetic moment,=n*(n+2)=4*6 = 4.89BM    Since the magnetic moment is not equal tozero, it is paramagnetic.    Since the magnetic moment is not equal tozero, it is paramagnetic.       SoRuO is having paramagnetic nature . b) The given compound is CuCl       Here Cu oxidation state is+1 state (Cu+)       The stable Electroniccofiguration of (Cu+) is3d104s0       Here the number ofUnpaired electrons is 0       So=0.0 BM    Since magnetic moment is equal to zero, itis diamagnetic.    Since magnetic moment is equal to zero, itis diamagnetic.      So CuClis having diamagnetic nature . c) The given compound is NiCl2         Here Nioxidation state is +2 state (Ni2+ )       The Electronic cofiguration ofNi2+is 3d84s0       Here the number ofUnpaired electrons is 2      =n*(n+2)=2*4 =2.82 BM       SoNiCl2 is having paramagnetic nature . d) The given compound is Mo2O3       Herethe oxidation state of Mo is +3       Theelectronic configuration of Mo3+ is4d35s0      Here thenumber of Unpaired electrons is  3      =n*(n+2)=3*5 =3.87BM       SoMo2O3 is havingparamagnetic nature . e) The given compoundis  NbCl5       Herethe oxidation state of Nb is +5       The electronicconfiguration of Nb+5 is4d05s0      Here thenumber of Unpaired electrons is 0      So =0.0 BM      So   NbCl5 is having diamagneticnature      Here thenumber of Unpaired electrons is  3      =n*(n+2)=3*5 =3.87BM       SoMo2O3 is havingparamagnetic nature . e) The given compoundis  NbCl5       Herethe oxidation state of Nb is +5       The electronicconfiguration of Nb+5 is4d05s0      Here thenumber of Unpaired electrons is 0      So =0.0 BM      So   NbCl5 is having diamagneticnature       Herethe oxidation state of Nb is +5       The electronicconfiguration of Nb+5 is4d05s0      Here thenumber of Unpaired electrons is 0      So =0.0 BM      So   NbCl5 is having diamagneticnature      So =0.0 BM      So   NbCl5 is having diamagneticnature