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, What is the oxidation state of the copper in the complex (CuCHOn? b. +2 d. 14

ID: 694862 • Letter: #

Question

, What is the oxidation state of the copper in the complex (CuCHOn? b. +2 d. 14 16 j. None of the above 7. What is the coordination number and the oxidation state for the following compound Fe(en) JCh (where en is ethylene diamine NH CH CH,NH). a 6,6 .6,+3 b. 6,+4 d. 6,+2 e. 4, +4 r.4,+3 2 4, +2 i. 2,+3 8. How many isomers does (Fefen),JCl, (include all diastereomers and enantiomers) d. 4 Directions for the next 3 problems. Give the number of unpaired electrons for the following compounds 9 Fe(CN)) (iron complexes can be both high and low spin, depending on ligand. Choose the most likely here using the electrochemical series) i. Can't tell j. None of the above d. 3 h. 7 1O, PICKONH)y (recall that in a square planar field only the 2 orbitals lowest in energy are degenerate) i. Can't tell j. None of the above 4 b.Id 3 h. 7 II. K [RuFoj (high spin) g. 6 h. 7 i. Can't tell j. None of the above e. d. 3 12. Based on electron configuration, and assuming no charge transfer absorption, which is most likely colorless? a. (Cu(NH3)4]" b (CoChiCN)) ch%) d, [Ni(CO)4" f. They are all colored 13. Put the following in the order of their boiling points, from lowest to highest. 1H.0, GeHa, CHa, Snfa, SiH, d. CHs, SiH4, GeHa, SnHa, HO e. SnHa, GeH, SiH, CHa, HO b. H,O, CHa, Sill, GeH, SnH e. H:O, SnH, Gel, SiHs, CH 14. Of the following molecules which are completely planar (all of the atoms in the molecule are located in the same plane, all the time)?

Explanation / Answer

6)
oxidation state of Cl is -1 and there are 2 Cl
oxidation state of H2O is 0
To balance charge, oxidation state of Cu is +2
Answer: b

7)
en is bidentate ligand
So, 2 en means there are cordination number of 4
charge of Cl is -1 and there are 3 Cl atoms
en is neutral
To balance charge, oxidation state of Fe is +3
Answer: f

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