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[Review Topics References Use the References to access important values if neede

ID: 705567 • Letter: #

Question

[Review Topics References Use the References to access important values if needed for this question. For the reaction below CH3CH2-H + HO-OH CH3CH2-OH H-OH + + ed a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your te Cliek the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units b. Is the reaction exothermic or endothermic? c. Is the reaction likely to proceed spontaneously in the direction written? Submit Answer Retry Entire Group 9 more group attempts remaining

Explanation / Answer

For the given reaction,

(a) Using bond enthalpy

dHrxn = dH(reactants) - dH(products)

           = (413 + 146) - (358 + 463)

           = -262 kJ/mol

(b) It is an exothermic reaction as dH is -ve.

(c) Reaction is spontaneous

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For the given reaction,

(a)

dHrxn = dH(reactants) - dH(products)

           = 413 - 565

           = -152 kJ/mol

(b) It is an exothermic reaction as dH is -ve.

(c) Reaction is spontaneous

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For the given reaction,

(a)

dHrxn = dH(reactants) - dH(products)

           = 413 - 463

           = -50 kJ/mol

(b) It is an exothermic reaction as dH is -ve.

(c) Reaction is spontaneous

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Products for the ether cleavage reaction,

CH3CH2OH + CH3I

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Products for the E2 elimination reaction are,

CH3-CH=CH-CH3 + CH3OH + Br-

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