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I believe this problem has the order of reactionsincorrect. CH3 is a ortho/para

ID: 75067 • Letter: I

Question

I believe this problem has the order of reactionsincorrect. CH3 is a ortho/para director (donates electronsvia hyperconjugation), so you cant get m-nitrotoluene in the secondstep, you would get p-nitrotoluene. Instead, I believe youneed oxidize the CH3 with KMnO4 or dichromate, yielding the COOHgroup, which is a meta-director. Nitration proceeds fromthere as normal to yield n-nitrobenzoic acid. Thanks for the review, Alexander Herbst I believe this problem has the order of reactionsincorrect. CH3 is a ortho/para director (donates electronsvia hyperconjugation), so you cant get m-nitrotoluene in the secondstep, you would get p-nitrotoluene. Instead, I believe youneed oxidize the CH3 with KMnO4 or dichromate, yielding the COOHgroup, which is a meta-director. Nitration proceeds fromthere as normal to yield n-nitrobenzoic acid. Thanks for the review, Alexander Herbst

Explanation / Answer

You need to post this as a Challenge to the solution.  You can do it like this.  Enter the solution, on the top there are several tabs.  Click the tab that says Challenge.  Copy and paste what you just wrote in there, and the cramster people will look over it and if they think you are right they will fix it and give you karma points.

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