Please Show Work if possible A. Calculate deltaGrxn for the reaction below at 25
ID: 796421 • Letter: P
Question
Please Show Work if possible
A.
Calculate deltaGrxn for the reaction below at 25C
2Ca(s) + O2(g) = 2CaO(s)
given:
deltaH'rxn= -1270.2 kJ
deltaS'rxn= -211.9J/K
a) -1058.3 kj b) -1207.0 kj c) -1333.4 d) -1482.1 kj
B.
Given that
C(s) + O2(g) = CO2(g) DeltaG'= -394.4 kj
CO(g) + 1/2O2(g) = CO2(g) DeltaG'= -257.2kj
Calculate deltaG' for the following reaction.
2C(s) + O2(g) = 2CO(g)
a) -651.6 kJ b) -274.4 kJ c) -137.2 kJ d) +137.2 kJ e) +274.4 kJ
C.
For a chemical system deltaS' and deltaS are equal when
a) the system is in equilibrium.
b) the reactants and products are in standard state conditions.
c) deltaG' and delta G are both positive.
d) the reactants are elements.
e) the reactants and products are in the gas phase.
Explanation / Answer
This is a simple gibbs energy equation
where delta g = deltaH - T * deltaS
therefore, deltaG = -1270200 - (298) (-211.9) = -1207053.8kJ = b). -1207.0 kJ
2).This is a hess law question
C + O2 --> CO2 ---(1).
CO + 1/2 O2 --> CO2 ---(2).
To get 2C + O2 --> 2CO as final equation
we add 2* (1) - 2 *(2) which cancels out 2 CO2 and 1 O2 molecule to give the fuinal equation
delta G follows the same rule as the equations
Therefore Delta G (net) = 2 * delta G1 - 2 * delta G2 = - 274.4 kJ
if delta S' and delta S are equal
it implies that
the system is in equilibrium
Rest all the options are false.
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