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The thermal decomposition of nitryl chloride, NO2Cl, is believed to occur by the

ID: 807609 • Letter: T

Question

The thermal decomposition of nitryl chloride, NO2Cl, is believed to occur by the following mechanism:
NO2Cl(g)?NO2(g)+Cl(g)Cl(g)+NO2Cl(g)?NO2(g)+Cl2(g)

Part A

What is the overall reaction?

What is the overall reaction?

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Part B

What is the molecularity of the first elementary step?

What is the molecularity of the first elementary step?

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Part C

What is the molecularity of the second elementary step?

What is the molecularity of the second elementary step?

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Part D

What rate law is predicted by this mechanism if the first step is rate-determining?

What rate law is predicted by this mechanism if the first step is rate-determining?

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NO2Cl(g)?NO2(g)+Cl2(g) 2NO2Cl(g)?2NO2(g)+Cl2(g) 2NO2Cl(g)?NO2(g)+Cl2(g) NO2Cl(g)?2NO2(g)+Cl2(g)

Explanation / Answer

Part A Overall reaction

2NO2Cl(g) -- > 2NO2 + Cl2(g)

Part B Unimolecular

Part C Bimolecular

Part D Rate = k[NO2Cl]

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