The solubility of limestone, CaCO3, at 25oC is 0.00067 g/100 mL. Write the chemi
ID: 811025 • Letter: T
Question
The solubility of limestone, CaCO3, at 25oC is 0.00067 g/100 mL. Write the chemical equation for the solubility equilibrium of this soluble salt in water. Then compute the molar solubility and the solubility product constant Ksp for CaCO3 at 25 degrees Celcius. The solubility of limestone, CaCO3, at 25oC is 0.00067 g/100 mL. Write the chemical equation for the solubility equilibrium of this soluble salt in water. Then compute the molar solubility and the solubility product constant Ksp for CaCO3 at 25 degrees Celcius.Explanation / Answer
CaCO3 -------> Ca2+ + CO32-
Ksp = [Ca2+]*[CO32-]
Here [Ca2+] = [CO32-] = s
Molar Solubility is moles per 1000 ml
So
s = (0.00067*10/100) mol/L
s = 6.7*10^-5 mol/L
Therefore
Ksp = s^2
= (6.7*10^-5)^2
= 4.489*10^-9
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