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The kinetics of the reaction between chlorine dioxide and ozone are relevant to

ID: 813619 • Letter: T

Question

The kinetics of the reaction between chlorine dioxide and ozone are relevant to the study of atmospheric ozone destruction. The value of the rate constant for the reaction between chlorine dioxide and ozone was measured at four temperatures. The results are as follows:

1)Calculate the value of the activation energy

kJ/mol

2)Calculate the frequency factor for the reaction.

kJ/mol

2)Calculate the frequency factor for the reaction.

The kinetics of the reaction between chlorine dioxide and ozone are relevant to the study of atmospheric ozone destruction. The value of the rate constant for the reaction between chlorine dioxide and ozone was measured at four temperatures. The results are as follows: 1)Calculate the value of the activation energy kJ/mol 2)Calculate the frequency factor for the reaction.

Explanation / Answer

If you use the Arrhenius equation and plot 1/T vs ln(k) you'll get the scope (Ea/R) and the role (lnA)

ln(K) = ln (A) - Ea/R* (1/T)

Fit the line to a linear equation:

y = -4698,7 X + 27,872 where y =lnK and x= 1/T

Ea / R = 4698,7

Ea = 4698,7 * 8,314472 J/K*mol =39067, 2 J/K*mol = 3,9 kJ / K*mol

ln (A) = 27,872 ----> A= exp(27,872) = 1.272 *1012

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