Question 7 What is the solubility of Al 3+ at pH = 4.45 if solubility is limited
ID: 836305 • Letter: Q
Question
Question 7
What is the solubility of Al3+ at pH = 4.45 if solubility is limited by formation of the hydroxide? (Ksp Al(OH)3 = 3.1 x 10-34, Kw = 1.0 x 10-14)
3.8 x 10-9 M
0.042 M
6.4 x 10-3 M
3.1 x 10-34 M
1.4 x 10-5 M
1 points
Question 8
Which of the following statements is not true?
Chemical oxygen demand values are typically higher than biological oxygen demand values for the same sample.
Fe2+ is significantly more soluble in water than Fe3+
In O2-saturated water, the reduction of O2 to water is the half-reaction that dominates pE.
Water hardness is a measure of the concentration of calcium and magnesium ions in solution
Water in equilibrium with CO2 but not CaCO3 is expected to have an alkaline pH
3.8 x 10-9 M
0.042 M
6.4 x 10-3 M
3.1 x 10-34 M
1.4 x 10-5 M
Explanation / Answer
pH = 4.45 , pOH = 14-4.45 =9.55 ,, [OH-] = 10^-9.55 = 2.8184 x 10^-10
Ksp = 3.1 x 10^-34 = [Al3+][OH-]^3
3.1 x 10^-34 = [Al3+][2.8184 x 10^-10) ^3
[Al3+] = 1.384 x 10^-5 M = 1.4 x 10^-5 M ( rounded value)
2) Fe2+ is more solube in water than Fe3+ statement is wrong since Fe3+ forms more soluble hydroxide compared to Fe2+ hydroxide.
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