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NH4Br FeCl3 KCH3COO Al(NO3)3 CaF2 BaSO3 H2C6H2O5 (aq) is amphiprotic. Write equa

ID: 840525 • Letter: N

Question

NH4Br FeCl3 KCH3COO Al(NO3)3 CaF2 BaSO3 H2C6H2O5 (aq) is amphiprotic. Write equations for how it can react as 1) an acid with water and 2) a base with water. Describe how the common ion effect is an example of LeChatelier's Principle. Why must the pKa of the weak acid be consider when selecting a conjugate acid-base pair to use when making a buffer at a desired pH? List 3 ways the titration curve of a strong acid-strong base is different from the titration curve of a weak acid-strong base. Describe how to find the equivalence point on a titration curve. The Ksp of AgI is 8.3 times 10-17. What is the solubility (in mol/L) of AgI? (See Sample Exercise 17.11) The Ksp of PbCl2 is 1.7 times 10-5. What is the solubility (in mol/L) of PbCl2? The Ksp of Ca3(PO4)2 is 2.0 times 10-29. What is the solubility (in mol/L) of Ca3(PO4)2? Calculate the solubility of CuBr in a solution that is 0.01 in M KBr. Ksp- of CuBr = 5.3 times 10-12 Calculate the solubility of Ag2CrO4 in a solution that is 0.01 M in AgNO3. Ksp of Ag2CrO4 = 1.210-12 Use LeChatelier's Principle to explain why the solubility of a compound containing a basic anion (that is, the anion of a week acid) increases as the solution becomes more acidic.

Explanation / Answer

I have less time so solving them asap :-

19] H2C6H7O5-

acid ---> HC6H7O52-

base ----> H3C6H7O5

21] because a weak acid will not dissociate completely to give H+ ions in the solution so we need to consider the H+ from water also and from the acid too

22]the titration curve of a this changes at low and high pH values this is the amjor difference b/w the two one in a basic region and the other in a acidic region

23]the equivalence poi nt can be found by the change in colour of the solution by obervation and from the graph

pKa1+ pKa2/2 = equivalence point

24]AgI

Ksp = s^2

s^2 = 8.3*10^-17

solve for s

25]pbCl2

4s^3 = 1.7*10^-5

solve for s

26] 2.0*10^-29 = 27s^3 * 4s^2

= 108s^5 = Ksp

solve for s

27] 5.3* 10^-12 = s* (s+0.01)

neglect s in comparison to 0.01

so we get

s* 0.01 = 5.3* 10^-12

28]do same as no.27

friend i had less time so i solved it for you asap and i couldnt use the calculator to find the value if ny doubt feel free to ask ! happy to help you !