In acidic solution, the iodate ion can be used to react with a number of metal i

Question

In acidic solution, the iodate ion can be used to react with a number of metal ions. One such reaction is

IO3?(aq)+Sn2+(aq)?I?(aq)+Sn4+(aq)

Since this reaction takes place in acidic solution, H2O(l) and H+(aq) will be involved in the reaction. Places for these species are indicated by the blanks in the following restatement of the equation: IO3?(aq)+Sn2+(aq)+     ????I?(aq)+Sn4+(aq)+     ???

A .... What are the coefficients of the reactants and products in the balanced equation above? Remember to include H2O(l) and H+(aq) in the appropriate blanks. Your answer should have six terms. Please explain

Basic solution

Potassium permanganate, KMnO4, is a powerful oxidizing agent. The products of a given redox reaction with the permanganate ion depend on the reaction conditions used. In basic solution, the following equation represents the reaction of this ion with a solution containing sodium sulfite:

MnO4?(aq)+SO32?(aq)?MnO2(s)+SO42?(aq)

Since this reaction takes place in basic solution, H2O(l) and OH?(aq) will be shown in the reaction. Places for these species are indicated by the blanks in the following restatement of the equation: MnO4?(aq)+SO32?(aq)+     ????MnO2(s)+SO42?(aq)+     ???

B.......What are the coefficients of the reactants and products in the balanced equation above? Remember to include H2O(l) and OH?(aq) in the blanks where appropriate. Your answer should have six terms.

Explanation / Answer

A.

reaction will be:

IO3?(aq) + 6H+ + 6e ? I?(aq) + 3H2O
Sn2+(aq) ? Sn4+ + 2e ......................... x3

3Sn2+(aq) ? 3sn4+ + 6e

lets add above equation to remove electrons.

IO3?(aq) + 3Sn2+(aq) + 6H+ ? I?(aq)+ 3Sn4+(aq) + 3H2O

B.

MnO4- + 4 H+ + 3e- ? MnO2 + 2 H2O --------------------------x2
SO32- + H2O ? SO42- + 2 H+ + 2e-   -------------------------------x3
on adding them
2 MnO4- + 2H+ + 3 SO32- = 2 MnO2 + 3 SO42- + H2O


on adding 2 H+ on the left and

we know that 2 H+ + 2OH- ? 2 H2O .

so final equation is:

2 MnO4- + 3 SO32- + H2O ? 2 MnO2 + 3 SO42- + 2 OH-

Related Questions

Navigate

• Browse (All)
• Browse I
• Subjects

Integrity-first tutoring: explanations and feedback only — we do not complete graded work. Learn more.