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PART 1 A fictional company has been producing propene oxide, C3H6O, from propene

ID: 849272 • Letter: P

Question

PART 1

A fictional company has been producing propene oxide, C3H6O, from propene, C3H6, with a 96.0% yield. The process requires the use of a compound called m-chloroperoxybenzoic acid, C7H5O3Cl, which can be abbreviated as mCPBA. The entire reaction takes place in the solvent dichloromethane, CH2Cl2:

C3H6+C7H5O3ClCH2Cl2--->C3H6O+C7H5O2Cl

The initial propene concentration in the solvent is 21.0 g/L.

Consider the prices of the following substances.

Also consider that the cost of waste disposal is $5.00 per kilogram of propene oxide produced.

A relatively simple way of estimating profit is to consider the the difference between the cost (the total spent on materials and waste disposal) and the earnings (the price at which the product can be sold).

1. Calculate the profit from producing 47.00kg of propene oxide.

Express your answer numerically in dollars using three significant figures.

PART 2

The company is developing a "greener" method of making propene oxide from propene using hydrogen peroxide, H2O2, in supercritical water with a vanadium catalyst. In the reaction 1.00 kg of vanadium catalyst and 32.0 kg of water are used for each kilogram of propene. 75 % of the vanadium catalyst can be collected and reused in a subsequent batch:

C3H6+H2O2V, H2O--->C3H6O+H2O

Consider the prices of the following substances.

There is virtually no waste produced with this green process and there is no waste disposal fee, but the yield is only 89.0%.

2. Calculate the profit from producing 47.00kg of propene oxide by this alternative green process.

Express your answer numerically in dollars using three significant figures.

Substance Price per unit Unit propene $10.97 kg dichloromethane $2.12 L mCPBA $5.28 kg propene oxide $258.25 kg

Explanation / Answer

here is the similar question that I have done earlier

A fictional company has been producing propene oxide, C3H6O, from propene, C3H6, with a 96.0% yield. The process requires the use of a compound called m-chloroperoxybenzoic acid, C7H5O3Cl, which can be abbreviated as mCPBA. The entire reaction takes place in the solvent dichloromethane, CH2Cl2:

The initial propene concentration in the solvent is 21.0 g/L.
Consider the prices of the following substances:

Substance Price per unit Unit
propene $10.97 kg
dichloromethane $2.12 L
mCPBA $5.28 kg
propene oxide $258.25 kg

Also consider that the cost of waste disposal is $5.00 per kilogram of propene oxide produced.

A relatively simple way of estimating profit is to consider the the difference between the cost (the total spent on materials and waste disposal) and the earnings (the price at which the product can be sold).

Calculate the profit from producing 75.00kg of propene oxide...

soln....>>

on page 4 of: http://faculty.missouri.edu/~glaserr/216...
it shows that 1mol mCPHA provides the oxygens to 1 mol of propene, to make 1 mole of C3H6O
so: 1 mol C3H6 & 1 mol mCPHA --> 1 mol C3H6O

using molar masses, that equation becomes:
42.08grams C3H6 & 172.57grams mCPHA --> 58.08grams C3H6O
which is: 42.08 kg C3H6 & 172.57 kg mCPHA --> 58.08 kg C3H6O

to produce 1 kg of C3H6O, this becomes:
42.08 / 58.08 kg C3H6 & 172.57 / 58.08 kg mCPHA --> 58.08 /58.08 kg C3H6O
which is: 0.72452 kg C3H6 & 2.9712 kg mCPHA --> 1 kg C3H6O

but because the reaction gives only a 96% yield,
we scale up the reactants to get that desired 1 kg of C3H6O
(0.72452 kg ) (100/96) C3H6 & (2.9712 kg) (100/96) mCPHA --> 1 kg C3H6O
which is: 0.75471 kg C3H6 & 3.095 kg mCPHA --> 1 kg C3H6O

=========
costs per kg of C3H6O produced:

(0.75471 kg C3H6) ($10.97 per kg) = $8.279
(3.095 kg mCPHA) ($5.28 per kg) = $16.342
&
(0.75471 kg C3H6) / (0.0210 kg C3H6 / L dichloromethane) = 35.939 Litres dichloromethane
(35.939 Litres dichloromethane) ($2.12 per L) = $ 76.19
&
waste disposal is $5.00 per kilogram of propene oxide produced

total cost, disregarding labor,energy, & facility costs:
$8.279 & $16.342 & $ $ 76.19 & $5.00 = $105.81 per kg C3H6O produced

==========

profit: ($258.25 / kg C3H6O) - ($105.81 cost per kg) = $152.44 profit /kg