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In Part B of Lab 11, you measured the voltage of several galvanic cells. Assembl

ID: 864811 • Letter: I

Question

In Part B of Lab 11, you measured the voltage of several galvanic cells.

Assemble a battery, represented by the diagram below with the cathode in compartment A, with Sn2+/Sn and Cu2+/Cu couples in which the voltage reads positive. (Use the Standard Reduction Potentials Table. Use the lowest possible coefficients. Omit states-of-matter from your answer.)

(a) What half-reaction occurs in compartment A?

(b) What half-reaction occurs in compartment B?

(c) Write the net redox reaction.

PLEASE SHOW YOUR WORK AND IF NECESSARY PROVIDE ANY EXPLANATION OF YOU THINK IT WOULD AIDE IN UNDERSTANDING THE QUESTION. THANK YOU

Explanation / Answer

a) oxidation reaction occur in compartment A

   Sn(s) ----------------------> Sn+2 (aq) + 2e-

b) reduction reaction occur in compartment B

    Cu+2(aq) + 2e- --------------------------> Cu(s)

c)   net redox reaction

Sn(s) + Cu+2(aq)   ----------------> Sn+2 (aq) + Cu(s)

d) cell potential

E0cell= E0cathode- E0anode

E0cell= E0Cu+2/Cu- E0Sn+2/Sn

          = 0.34 - (-0.14)

          = 0.48 V

(note : E0Cu+2/Cu = 0.34 V   , E0Sn+2/Sn = -0.14 V   at standard condition )

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