1.) Draw the major organic product of the reaction shown below. OH NaH You do no

Question

1.) Draw the major organic product of the reaction shown below. OH NaH You do not have to consider stereochemistry. Include counter-ions, e.g., Na I, in your answer, but draw them in their own sketcher Separate structures with signs from the dropdown menu [Review Topics] [References] 2.) Draw the major organic product of the reaction shown below. OH Dess-Martin periodinane 2 You do not have to consider stereochemistry. You do not have to explicitly draw H atoms Do not include lone pairs in your answer. They will not be considered in the grading

Explanation / Answer

1) The compound is 1'oxy-1-butylbenzol, and it is a secondary alcohol. It reacts with sodium hydride (i.e. NaH), which is a strong base, to form an anionic nucleophile.

C6H5CH(OH)CH2CH2CH3 + NaH ---------------->  C6H5CH(O-Na+)CH2CH2CH3

2) The starting compound is 2-Methyl-1-propanol. In this example of the Dess–Martin oxidation, involves transforming a secondary alcohol to its corresponding aldehyde.

CH3-CH(CH3)CH2OH ---------------------------> CH3-CH(CH3)CHO

2-Methyl-1-propanol 2-methyl-propanal   

Related Questions

Navigate

• Browse (All)
• Browse 1
• Subjects

---

---

Integrity-first tutoring: explanations and feedback only — we do not complete graded work. Learn more.