13. Let\'s work through a more complicated example of a rate law where the rate

Question

13. Let's work through a more complicated example of a rate law where the rate leermining surp i we first reaction. overall HCi Cela and the following infirmmation tiven are the elementary stepi for this reaction erou might discover someriing about reaction ordera) first a. Write the rate law for the overnll rcaction, b. What do you notice about the Ci substance? e. Using Reaction 1. find out what ICI is equal to, d. After solving for tcy. write the revised rate law for the overall reaction (ak.a. the actual TRUE rate law for this reaction). What is the overall reaction order for this reaction?

Explanation / Answer

a) second order reaction

b) Cl is intermediate

c) [Cl] = -I/k(d Cl2/dt)

d) rate = k[CHCl3][Cl2]1/2

e) over all order of reaction is 1.5

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