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Data Table 1. Varying Concentrations of 1.0 M HCl. Concentrations # of drops # o

ID: 878030 • Letter: D

Question

Data Table 1. Varying Concentrations of 1.0 M HCl.

Concentrations

# of drops

# of drops

# of drops

Stock Solution

Stock Solution

Reaction (after mixing in well)

Reaction (after mixing in well)

Reaction Time

(seconds)

Reaction

Rate

(sec-1)

Well #

HCl

H2O

Na2S2O3

HCl

Na2S2O3

HCl

Na2S2O3

Trial 1

Trial 2

Average

C1, D1

12

0

8

1M

0.3M

27.44

27.40

27.42

C2, D2

6

6

8

1M

0.3M

31.66

31.68

31.67

C3, D3

4

8

8

1M

0.3M

46.90

46.98

46.94

Data Table 2. Varying Concentrations of 0.3 M Na2S2O3.

Concentrations

# of drops

# of drops

# of drops

Stock Solution

Stock Solution

Reaction (after mixing in well)

Reaction (after mixing in well)

Reaction Time

(seconds)

Reaction

Rate

(sec-1)

Well #

HCl

H2O

Na2S2O3

HCl

Na2S2O3

HCl

Na2S2O3

Trial 1

Trial 2

Average

C4, D4

8

0

12

1M

0.3M

19.96

19.64

19.8

C5, D5

8

6

6

1M

0.3M

48.69

48.63

48.66

C6, D6

8

8

4

1M

0.3M

134.62

134.65

134.64

Reaction Order and Rate Laws                                                ^                 ^                                                           ^
Need help with finding the reaction after mixing well for Hcl and Na2S2O4 and the reaction rate (sec). How do you find??

and

Determine the Reaction Order for HCl using calculations described in the background section.Show your work. Note that your answer will probably not be an even whole number as it is in the examples, so round to the nearest whole number.

Concentrations

# of drops

# of drops

# of drops

Stock Solution

Stock Solution

Reaction (after mixing in well)

Reaction (after mixing in well)

Reaction Time

(seconds)

Reaction

Rate

(sec-1)

Well #

HCl

H2O

Na2S2O3

HCl

Na2S2O3

HCl

Na2S2O3

Trial 1

Trial 2

Average

C1, D1

12

0

8

1M

0.3M

27.44

27.40

27.42

C2, D2

6

6

8

1M

0.3M

31.66

31.68

31.67

C3, D3

4

8

8

1M

0.3M

46.90

46.98

46.94

Explanation / Answer

calculate moles of both reactants.

calculate the one in excess

convert to Molar concentration of each

Na2S2O3 + 2 HCl = H2O + 2 NaCl + S + SO2

1 mole of Na2S2O3 reacts with 2 moles of HCl

Its not specified how many ml is 1 drop.

It is thus difficult to calculate the concentration of each in the final solution and hence the rate.

The unit of rate suggests it is a first order reaction,

thus,

Rate = k[A]

ln[A]t = -kt + ln[A]o

Find k

substitute in the rate equation to find the rate