Please provide complete correct and detailed mathematical solution. This is all
ID: 897732 • Letter: P
Question
Please provide complete correct and detailed mathematical solution. This is all the information provided. Thank you.
The oxidation of propene (P) to acrolein (A) was carried out over a Mo-Pr-Bi catalyst: It has been proposed that this mechanism can be correlated to a power law of the form: The reaction was carried out in a differential reactor with 0.5 g of catalyst at 623 K. From the data below determine the reaction orders with respect to propene and acrolein ( alpha and beta ), as well as the rate constant at this temperature.Explanation / Answer
we need to determine the values of alpha and beta
let alpha =x and beta=y.so,
rate=Fa (since it is the rate).so,
there are three unknows, k, x and y.Hence,
rate=k*(Pp)^x*(Po2)^y
for the case 1:
0.21=k*0.1^x*0.1^y
for the case 2,
0.48=k*0.2^x*0.2^y
for the third case,
0.39=k*0.3^x*0.01^y
solving, we get
x=alpha=0.987
y=beta=0.203
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