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, PROBLEM SET 6 (20 points) 09-105 Fall 2015 Name tion (CIRCLE Re, Number, Recit

ID: 923257 • Letter: #

Question

, PROBLEM SET 6 (20 points) 09-105 Fall 2015 Name tion (CIRCLE Re, Number, Recitation (CIRCLE BELOW ONE TA and ONE TIME: Yookie (A,B) Annie (CD) Eric (EF) Paul (GJH) Meredith J) DUE TUESDAY 1211 BY 6 PM at the drophox outside of DII 2303 dnterdiner4 2. Below are the approximated pictures of the LCAO of unhybridized p orbitals that yie 6:30 7:30 lds only MO's for NO2 (a) Circle the MO picture representing a LC4O bonding MO. Question to consider: What is the most distinguishing property of a bonding C-i4) MO? 888"888, 88-88- LCAo (b) Place a rectangle around the MO picture representing a antibonding MO Question to consider: What is the most distinguishing property of an antibonding MO? LCAO (c) What type of MO is the remaining MO picture around which you did not place a circle or a rectangle. O 2003 Thomson-Brooks/Cole (d) How many electrons occupy a hybrid orbital not involved in bonding? (e) Below are the energy levels of the -only MO's of NO. (1) Draw an arrow pointing to the * MO's energy level. Question to Consider: what is the relative energy of this type of MO among other MO's? (f) Briefly explain why there are 3 type MOs involved in using MO Theory to describe the delocalized bonding electrons of NO2 Question to Consider: How many unhybridized p orbtials are available after applying hybridization to each of the atoms? 4

Explanation / Answer

, PROBLEM SET 6 (20 points) 09-105 Fall 2015 Name tion (CIRCLE Re, Number, Recit