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Pre-laboratory Questions 1. A solution is saturated with H,S at a concentration

ID: 953302 • Letter: P

Question

Pre-laboratory Questions 1. A solution is saturated with H,S at a concentration of 0.10 M and is 0.00020 M in each of the metal cations Co, Fe Mn', Ni 2, and Zn"2. At a pH of 3.0, which of the metal cations will precipitate as the su lfide? (HINT: Calculate IP) Metal Sulfide ZnS CoS Nis FeS MnS 3×10-2 5×10-1 4 × 10, 6× 102 3 × 10' 2. Under the conditions given in the preceding question, what pH is needed to pre- cipitate as much of the Zn ,Co2, and Ni 2 as possible without precipitating the Fe*2 and Mn?

Explanation / Answer

1)

Answser:

The compound which has lower Ksp will form the precipitate first.

in the above table ZnS has lowest Ksp ,so it precipitate first.

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