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The molecule decalin consists of two fused cyclohexane rings. It can exist in a

ID: 958653 • Letter: T

Question

The molecule decalin consists of two fused cyclohexane rings. It can exist in a cis-form or Trans-form, as shown below. Illustrate the following for each of the two isomers, keeping in mind that you will need to use a model kit in Autre to test confirmational flips: 1 The most stable sites for mono – substitution off one of the fused rings. 2 The most stable sites and are you orientation ( i.e. cis/trans, as well as axial/Equatorial) distribution of one of the rings. Keep in mind that the rings are themselves substituents off one another, and therefore contribution to the steric's strain in the molecules. Please help, thank you :) The molecule decalin consists of two fused cyclohexane rings. It can exist in a cis-form or a trans-form, as shown below. Illustrate the following for each of the two isomers, keeping in mind that you will need to use a model kit in order to test conformational flips: o-substitution of one of the fused rings. 1 The most stable sites for mon 2 The most stable sites and orientations (i.e. cis/trans, as well as axial/equatorial) for disubstitution of one of the rings. substituents of one another, and therefore Keep in mind that the rings are themselves contribute to the steric strain in the molecules. CAS

Explanation / Answer

Trans-decaline is more stable than cis-decaline since all carbons are equatorial in trans-decaline.

1 The most stable sites for mono – substitution off one of the fused rings is equatorial.

2 The most stable sites and orientation distribution of one of the rings is equatorial and axia (cis-decaline).

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