There are a number of terms used in conformational analysis. Match each term bel
ID: 985787 • Letter: T
Question
There are a number of terms used in conformational analysis. Match each term below with the appropriate definition?
conformational orientation in which designated groups have a 60 degree dihedral angle
conformational orientation in which designated groups have a 180 degree dihedral angle
conformational orientation in which adjacent groups have a zero dihedral angle
strain caused by two groups with less than 60 degree dihedral angle
strain caused by two groups more than three bonds apart that overap in space
most stable conformation of a six membered ring
conformation of a six membered ring with four eclipsing bonds
two structures that differ from each other only in rotations around sigma bonds
Questions///////// Selected Match 1. conformers A.conformational orientation in which designated groups have a 60 degree dihedral angle
2. gauche B.conformational orientation in which designated groups have a 180 degree dihedral angle
3. chair C.conformational orientation in which adjacent groups have a zero dihedral angle
4. boat D.strain caused by two groups with less than 60 degree dihedral angle
5. anti E.strain caused by two groups more than three bonds apart that overap in space
6. eclipsed F.most stable conformation of a six membered ring
7. steric G.conformation of a six membered ring with four eclipsing bonds
8. tortional H.two structures that differ from each other only in rotations around sigma bonds
Explanation / Answer
1) H
2) A
3) F
4) G
5) B
6) C
7) E
8) D
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