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1.) Consider the reaction 3A <===> 2B, where the value of K is 22.1. If the conc

ID: 1007899 • Letter: 1

Question

1.) Consider the reaction 3A <===> 2B, where the value of K is 22.1. If the concentration of A is 0.015 at equilibrium, what is the concentration of B?

2.) For the reaction

C(s) + CO2(g) <====> 2CO(g) Kc = 168,

determine whether the system is at equilibrium when [CO] = 0.50 M and [CO2] = 0.75 M. The system ____ at equilibrium, because ___.

3.) Consider the reaction A <===> B, where the value of Kc is 1.4 x 10–15. Which statement about the system at equilibrium is correct?

A. 6.5 x 106 B. 0.010 C. 1.0 D. 8.6 x 10-3 E. 7.5 x 10-5

Explanation / Answer

Q.1: Given [A]eq = 0.015

The given reaction is

3A <===> 2B: K = 22.1

K = 22.1 = [B]2 / [A]3

=> 22.1 =  [B]2 / (0.015)3  

=>  [B]2 = 22.1 x (0.015)3 =

=> [B] = 8.6x10-3 M (answer)

Option D is correct

Q.2: C(s) + CO2(g) <====> 2CO(g): Kc = 168

Q value for the above reaction is

Q = [CO(g)]2 / [CO2(g)] = (0.5)2 / (0.75) = 0.333

Hence Q < K,

However for a reaction to be in equilibrium, Q must be equal to K

Hence the system is not at equilibrium because Q = 0.33

Hence option A is correct.

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