A compound with on M* peak (also the base peaK) at 93 m/z shows the next largest

Question

A compound with on M* peak (also the base peaK) at 93 m/z shows the next largest peak at 66 m/z. There is almost no peak at m/z of 27 (93-66). What is the mast likely reason? To get credit, put the letter of the best answer here: A. The fragment with m/z of 27 rearranges. B. The fragment with m/z of 27 is a radical, not on ion. C. The fragment with m/z of 27 further fragments. D. The fragment with m/z of 27 combines with another fragment. What is the most likely functional groups in the compound with the IR spectra below? Indicate the absorbance bands that led you to your decision.

Explanation / Answer

A

When it rearranges no peaks at 27m/z

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