Questions: 1.Account for the increase in the values of the diamagnetic correctio
ID: 1025581 • Letter: Q
Question
Questions: 1.Account for the increase in the values of the diamagnetic corrections (Table 3-1) in going from the top to the bottom of any group in the periodic table. 2. The volume susceptibility of air is listed as 0.029 x 10 per mL. What causes its susceptibility to be positive? 3. If the standard were packed more compactly than the unknown, but both were packed evenly in the tube, how would this affect the calculated value of ? 4.When the bottom of the tube is at the centre of the pole faces, a Gouy tube containing [Ni(en)3]S203 has a certain weight in the magnetic field. If the magnet is raised so that the bottom of the tube is slightly below the centre of the pole faces, will the observed weight be more or less than in the original measurement? Explain.Explanation / Answer
Answer:
1. The dimagnetic correction in an element goes up or increases when their is a probability of more delocalization of p-electrons. As we go down the group, the empty d-orbitals of halogens increases therefore the tendency for delocalization and the valence orbital number also increases as we go down the group. this thus accounts for the increase in the value of dimagnetic correction in the halogen group series.
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